石墨烯基可见光催化材料的抗菌研究进展

doi:10.19784/j.cnki.issn1672-0172.2022.99.104

摘要/Abstract

摘要： 石墨烯因具有较强的化学稳定性、高比表面积及高导电性而在光催化领域表现出广阔的应用前景。综述石墨烯基可见光催化复合材料的抗菌性研究进展。首先介绍石墨烯基光催化材料的催化抗菌原理及石墨烯发挥的基础作用,即拓宽半导体材料的光吸收范围和强度、抑制光生电子-空穴的复合和吸附作用等。介绍了多种石墨烯基可见光催化材料的抗菌研究进展,包括TiO₂/石墨烯的二元型复合光催化材料（普通型、掺杂型、缺陷型）和三元复合型光催化材料以及其他半导体/石墨烯材料。最后指出石墨烯基可见光催化材料在冰箱除菌功能中具有广泛的应用前景,其在外加物理场增强作用下应用将进一步提升抗菌效果,与传感技术联用可进一步提升冰箱的智能除菌效果。

关键词: 石墨烯, 半导体, 可见光, 光催化, 抗菌, 冰箱

Abstract: Graphene shows a promising application potential in the field of photocatalysis due to the satisfactory performance, such as a strong chemical stability, high specific surface area and electrical conductivity. The antibacterial properties of graphene-based visible light catalytic composites were reviewed. Firstly, the photocatalytic antibacterial mechanism of graphene-based photocatalytic materials was briefly introduced, the positive role in the photocatalytic reaction process of graphene was summarized, including expanding range and intensity of light absorption, preventing the photoelectron-hole from recombining and facilitating the adsorption. The antibacterial research progress of various graphene-based visible light catalytic materials was introduced, including binary TiO₂/graphene composite (common, doping, defect), ternary composite and other semiconductor/graphene materials. Finally, it was pointed out that graphene-based visible light catalytic materials have a promising potential in the sterilization function of refrigerators. The application of graphene-based visible light catalytic materials under the effect of physical field would further improve the antibacterial effect, and the combination of sensor technology could further improve the intelligent sterilization function of refrigerators.

Key words: Graphene, Semiconductor, Visible light, Photocatalytic, Antibacterial, Refrigerator

中图分类号:

TB332

李雪, 王海燕. 石墨烯基可见光催化材料的抗菌研究进展[J]. 家电科技, 2022, 0(zk): 475-480.

LI Xue, WANG Haiyan. Research progress on antibacterial properties of graphene-based photocatalytic materials[J]. Journal of Appliance Science & Technology, 2022, 0(zk): 475-480.

参考文献

[1] 胡海梅, 张宇佳. 深紫外杀菌及应用于冰箱技术研究[J]. 家电科技, 2020(zk): 47-49.
[2] 王海燕, 胡哲, 周伟洪. 冰箱保鲜技术综述[J]. 电器, 2019(02): 24-25.
[3] MA Kausor, D Chakrabortty. Graphene oxide based semiconductor photocatalysts for degradation of organic dye in waste water: A review on fabrication, performance enhancement and challenges[J]. Inorganic Chemistry Communications, 2021, 129: 108630.
[4] NLM Tri, J Kim, DV Thuan, PT Huong, TMA Tahtamouni. Improved photocatalytic decomposition of methyl ethyl ketone gas from indoor air environment by using TiO₂/graphene oxide[J]. Materials Research Express, 2019, 6(10): 105509.
[5] Y Li, X Xiao, Z Ye, Fabrication of BiVO4/RGO/Ag₃PO₄ ternary composite photocatalysts with enhanced photocatalytic performance[J]. Applied Surface Science, 2019, 467: 902-911.
[6] M Tadashi, T Ryozo, N Toshiaki, W Hitoshi.Photo-electrochemical sterilization of microbial cells by semiconductor powders[J]. Fems Microbiology Letters, 1985(1-2): 211-214.
[7] 胡哲, 周伟洪, 朱雪峰, 王海燕. 光触媒模块在冰箱上的应用效果探究[J]. 家电科技, 2019(04): 72-76.
[8] YJ Shi, JX Ma, YN Chen, YK Qian, BX, WH Chu, DA. Recent progress of silver-containing photocatalysts for water disinfection under visible light irradiation: A review[J]. Science of The Total Environment, 2022, 804: 150024.
[9] M Ismael.Latest progress on the key operating parameters affecting the photocatalytic activity of TiO₂-based photocatalysts for hydrogen fuel production: A comprehensive review[J]. Fuel, 2021, 303: 121207.
[10] V Dutta, P Singh, P Shandilya, S Sharma, P Raizada, A K Saini, V K Gupta, A Hosseini-Bandegharaei, S Agarwal, A Rahmani-Sani.Review on advances in photocatalytic water disinfection utilizing graphene and graphene derivatives-based nanocomposites[J]. Journal of Environmental Chemical Engineering, 2019, 7(03): 103132.
[11] NT Padmanabhan, N Thomas,J Louis, DT Mathew, SC Pillai. Graphene coupled TiO₂ photocatalysts for environmental applications: A review[J]. Chemosphere, 2021, 271(07): 129506.
[12] C H Lin, WH Chen. Graphene Family Nanomaterials (GFN)-TiO₂ for the Photocatalytic Removal of Water and Air Pollutants: Synthesis, Characterization, and Applications[J]. Nanomaterials, 2021, 11(12): 3195.
[13] E Kusiak-Nejman, AW Morawski. TiO₂/graphene-based nanocomposites for water treatment: A brief overview of charge carrier transfer, antimicrobial and photocatalytic performance[J]. Applied Catalysis B: Environmental, 2019, 253: 179-186.
[14] A Bokare, S Chinnusamy, F Erogbogbo.TiO₂-graphene quantum dots nanocomposites for photocatalysis in energy and biomedical applications[J]. Catalysts, 2021, 11(03): 319.
[15] F Khan, M S Khan, S Kamal, M Arshad, S I Ahmad, SAA Nami. Recent advances in graphene oxide and reduced graphene oxide based nanocomposites for the photodegradation of dyes[J]. Journal of Materials Chemistry C, 2020, 8(45): 15940-15955.
[16] 雷绍民, 熊毕华, 郝骞, 郭高丽. 纳米TiO₂复合抗菌材料抗菌机理与研究进展[J]. 资源环境与工程, 2006, 20(04): 459-462.
[17] 王振翠. 二氧化钛纳米材料的制备及其对农药乐果的光催化性能研究[D]. 北京: 北京化工大学, 2015.
[18] BC Cao, SC, PY Dong, J Gao, J Wang. High antibacterial activity of ultrafine TiO₂/graphene sheets nanocomposites under visible light irradiation[J]. Materials Letters, 2013, 93: 349-352.
[19] J Liu, L Liu, H Bai, Y Wang, DD Sun. Gram-scale production of graphene oxide-TiO₂ nanorod composites: towards high-activity photocatalytic materials[J]. Applied Catalysis B: Environmental, 2011, 106: 76-82.
[20] L Liu, H Bai, J Liu, DD Sun. Multifunctional graphene oxide-TiO₂ -Ag nanocomposites for high performance water disinfection and decontamination under solar irradiation[J]. Journal of Hazardous Materials, 2013, 261: 214-223.
[21] A Raja, K Selvakumar, P Rajasekaran, M Arunpandian, S Ashokkumar, K Kaviyarasu, S Asath Bahadur, M Swaminathan.Visible active reduced graphene oxide loaded Titania for photodecomposition of ciprofloxacin and its antibacterial activity[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 564: 23-30.
[22] P Gao, AR Li, DD Sun, WJ Ng. Effects of various TiO₂ nanostructures and graphene oxide on photocatalytic activity of TiO₂[J]. Journal of hazardous materials, 2014, 279: 96-104.
[23] YN Chang, XM Ou, GM Zeng, JL Gong, CH Deng, Y Jiang, J Liang, GQ Yuan, HY Liu, X He. Synthesis of magnetic graphene oxide-TiO₂ and their antibacterial properties under solar irradiation[J]. Applied Surface Science, 2015, 343: 1-10.
[24] P Fernández-Ibáñez, MI Polo-López, S Malato, S Wadhwa, JWJ Hamilton, PSM Dunlop, R D’Sa, E Magee, K O’Shea, DD Dionysiou, JA Byrne. Solar photocatalytic disinfection of water using titanium dioxide graphene composites[J]. Chemical Engineering Journal, 2015, 261: 36-44.
[25] JJ Xu, ZL Tian, GH Yin, TQ Lin, FQ Huang.Controllable reduced black Titania with enhanced photoelectrochemical water splitting performance[J]. Dalton Transactions, 2017, 46: 1047-1051.
[26] 长沙理工大学. 一种羟基化氧化钛/石墨烯可见光催化材料的制备方法: 中国, CN105148894B[P].2015-12-16.
[27] A Biswas, G Salunke, P Khandelwal, R Das, P Poddar.Surface disordered rutile TiO₂-graphene quantum dot hybrids: a new multifunctional material with superior photocatalytic and biofilm eradication properties[J]. New Journal of Chemistry, 2017, 41(07): 2642-2657.
[28] 黄富强, 周策. 一种半导体广谱杀菌抗病毒复合材料和制备方法: 中国, CN111359642B[P].2021-06-11.
[29] 曾和平, 冯光, 胡梦云. 一种适用于光催化持续释放型的除味净味液体及制备方法: 中国, CN114289008A[P].2022-04-08.
[30] XF Yang, JL Qin, Y Jiang, R Li, Y Li, H Tang. Bifunctional TiO₂/Ag₃PO₄/Graphene composites with superior visible light photocatalytic performance and synergistic inactivation of bacteria[J]. Rsc Advances, 2014, 4(36): 18627-18636.
[31] 梁大宇. 石墨烯基半导体纳米复合材料的制备、表征及其光催化性能研究[D]. 杭州: 浙江理工大学, 2014.
[32] X Yang, J Qin, Y Jiang, K Chen, X Yan, D Zhang, R Li, H Tang. Fabrication of P25/Ag₃PO₄/graphene oxide heterostructures for enhanced solar photocatalytic degradation of organic pollutants and bacteria[J]. Applied Catalysis B: Environmental, 2015, 166-167: 231-240.
[33] C Liu, Y Lin, YF Dong, YK Wu, Y Bao, HX Yan, JZ Ma. Fabrication and investigation on Ag nanowires/TiO₂ nanosheets/graphene hybrid nanocomposite and its water treatment performance[J]. Advanced composites and hybrid materials, 2020, 3(03): 402-414.
[34] AK Mehdi, C Dhruba. Facile fabrication of N-TiO₂/Ag₃PO₄@GO nanocomposite toward photodegradation of organic dye under visible light[J]. Inorganic Chemistry Communications, 2020, 116: 107907.
[35] 李君建. 载银二氧化钛/石墨烯复合材料的制备及其催化杀菌性能的研究[D]. 太原: 中北大学, 2017.
[36] 朱慧娟. TiO₂为基础的复合材料光(光电)催化抗菌性能及机理研究[D]. 上海: 上海师范大学, 2017.
[37] X Ma, Q Xiang, Y Liao, T Wen, H Zhang.Visible-light-driven CdSe quantum dots/graphene/TiO₂ nanosheets composite with excellent photocatalytic activity for E. coli disinfection and organic pollutant degradation[J]. Applied Surface Science, 2018, 457: 846-855.
[38] HP Qi, HL Wang, DY Zhao, WF Jiang.Preparation and photocatalytic activity of Ag-modified GO-TiO₂ mesocrystals under visible light irradiation[J]. Applied Surface Science, 2019, 480: 105-114.
[39] HP Qi, HL Wang, DY Zhao.Facile synthesis of rGO-supported AgI-TiO₂ mesocrystals with enhanced visible light photocatalytic activity[J]. Nanotechnology, 2020, 31(37): 375701.
[40] H Teymourini, M Salavati-Niasari, O Amiri, F Yazdian.Application of green synthesized TiO₂/Sb2S3/GQDs nanocomposite as high efficient antibacterial agent against E. coli and Staphylococcus aureus[J]. Materials Science and Engineering: C, 2019, 99: 296-303.
[41] L Sun, T Du, C Hu, J Chen, J Lu, Z Lu, H Han.Antibacterial activity of graphene oxide/g-C3N4 composite through photocatalytic disinfection under visible light[J]. ACS Sustainable Chemistry & Engineering, 2017, 5: 8693-8701.
[42] 孙龙. 氧化石墨烯复合材料对病原菌的抗菌效应研究[D]. 武汉: 华中农业大学, 2016.
[43] A Malathi, J Madhavan, M Ashokkumar, P Arunachalam.A review on BiVO4 photocatalyst: Activity enhancement methods for solar photocatalytic applications[J]. Applied Catalysis A: General, 2018, 555: 47-74.
[44] 高品. 还原氧化石墨烯负载钨酸铋/二氧化钛复合可见光触媒抗菌材料及其制备方法: 中国, CN 110352983 A[P].2019-07-16.
[45] TF Tian, XZ Shi, L Cheng, YC Luo, ZL Dong, H Gong, LG Xu, ZT Zhong, R Peng, Z Liu. Graphene-based nanocomposite as an effective, multifunctional, and recyclable antibacterial agent[J]. ACS applied materials & interfaces, 2014, 6(11): 8542-8548.
[46] N Khadgi, AR Upreti, Y Li. Simultaneous bacterial inactivation and degradation of an emerging pollutant under visible light by ZnFe2O4 co-modified with Ag and rGO[J]. RSC Advances, 2017, 7: 27007-27016.
[47] D Xia, T An, G Li, W Wang, H Zhao, PK Wong. Synergistic photocatalytic inactivation mechanisms of bacteria by graphene sheets grafted plasmonic Ag AgX (X=Cl, Br, I) composite photocatalyst under visible light irradiation[J]. Water Research, 2016, 99: 149-161.
[48] G Wang, WJ Feng, XK Zeng, ZY Wang, CP Feng, DT McCarthy, A Deletic, XW Zhang. Highly recoverable TiO₂-GO nanocomposites for stormwater disinfection[J]. Water Research (Oxford), 2016, 94: 363-370.
[49] X Zeng, Z Wang, G Wang, TR Gengenbach, DT McCarthy, A Deletic, J Yu, X Zhang. Highly dispersed TiO₂ nanocrystals and WO₃ nanorods on reduced graphene oxide: Z-scheme photocatalysis system for accelerated photocatalytic water disinfection[J]. Applied Catalysis B: Environmental, 2017, 218: 163-173.